单项选择题

单原子分子A,B间发生反应,若忽略振动基态能量之差,则实验活化能Ea,临界能Ec,势垒Eb间存在关系为:()

A.Ea=Ec+1/2RT=Eb+1/2RT
B.Ea=Eb+1/2RT=Ec+RT
C.Ea=Ec-1/2RT=Eb-1/2RT
D.Ea=Eb+RT=Ec+RT